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李军辉

基本信息

李军辉

导师姓名: 李军辉
导师职称: 副教授
导师电话:
电子邮箱: lijunhui@xtu.edu.cn
办 公 室 : 化工学院A栋105室
个人主页: /a/teacher/lecturer/lijunhui/2017/1225/1906.html?1535802097

个人简介

李军辉,男,中共党员,博士,硕士生导师。2014年11月于同济大学物理化学专业博士毕业,先后在中国科学院上海高等研究院和惠生工程(中国)有限公司工作,曾主持企业研发项目,参与国家自然科学基金、上海市科委重大专项、上海市重大基础研究子课题、大型企业产学研技术应用开发等项目。2017年3月进入湘潭大学化工学院工作。目前主要从事多相催化及反应工艺的研究。近年来,在Journal of Catalysis、Chemical Communications、Catalysis Today、Industrial & Engineering Chemistry Research、Microporous and Mesoporous Materials、ChemCatChem、Catalysis Science & Technology、RSC Advances、Journal of Energy Chemistry等国际重要期刊上发表SCI论文;授权发明专利3项。

学习工作经历

2005-2009年,同济大学,本科,化学工程与工艺专业
2009-2014年,同济大学,博士,物理化学专业
2014-2015年 ,中国科学院上海高等研究院,低碳转化科学与工程中心,助理研究员
2015-2017年,惠生工程(中国)有限公司,研发工程师
2017年至今,湘潭大学,专任教师

主讲课程

《化工与生活》 《现代精细化工》

研究方向

1)煤化工、石油化工与精细化学品合成中高选择性的择形分子筛催化与反应工艺;
2)特殊形貌及孔结构分子筛绿色合成及应用;
3)新结构的多功能催化材料;

科研项目

1)主持国家自然科学基金青年基金项目"CO2耦合甲醇择形芳构化多功能分子筛催化剂的构筑", No.21802115, 2019.01-2021.12
2)主持湖南省自然科学基金青年基金项目“纳米片状Zn/ZSM-5合成及其甲醇择形芳构化合成PX多功能反应催化剂的研究”,No.2018JJ3501, 2018.01-2020.12
3)主持横向科研项目“核壳MFI分子筛的合成与择形乙基化性能研究”,2017.06-2019.05
4)主持湘潭大学博士科研启动项目“短孔道ZSM-5合成及其甲苯甲基化催化应用”,17QDZ13,2017.04-2019.12
5)主持企业研发项目,惠生工程(中国)有限公司工作期间
6)参与上海市科委重大专项“甲醇制芳烃催化剂与反应器关键技术研究与应用”,No.14DZ1203700,2014.10-2016.03
7)参与国家自然科学基金项目“煤液化重油加氢裂化反应特性与催化剂构效关系”,No.51174277,2012.01-2014.12
8)参与国家自然科学基金项目“择形催化中分子筛定向修饰方法研究”,No.20873091,2009.01-2011.12

著作


主要代表性论文

1. Junhui Li,* Qing Gong, Hua Lian, Linfang Ding, Zhonghua Hu, Zhirong Zhu. Transalkylation of C10 aromatics with 2-methylnaphthalene for 2,6-dimethylnaphthalene synthesis: High-efficiently shape-selective & synergistic catalysis over a multifunctional SiO2-Mo-HBeta catalyst. Journal of Catalysis, 2019, 378, 144-152.
2. Junhui Li, Yongtao Meng, Chao Hu, Hao Xiang, Luhao Cui, Zhixian Hao, Zhirong Zhu. Controlling reactive pathways in complex one-pot reactions using a novel shape-selective catalyst with multifunctional active-sites. Chemical Communications, 2018, 54, 11689-11692. (内封面)
3. Junhui Li,* Qing Gong, Hua Lian, Zhonghua Hu, Zhirong Zhu. New process for 2,6-dimethylnaphthalene synthesis by using C10 aromatics as solvent and transmethylation-agentia: High-efficiently & peculiar subarea-catalysis over shape-selective ZSM-5/Beta catalyst. Industrial & Engineering Chemistry Research, 2019, 58, 28, 12593-12601.
4. Junhui Li,* Qing Gong, Yifei Liu, Rongrong Kang, Chengguang Yang, Minghuang Qiu, Zhonghua Hu, Zhirong Zhu. Insight into the Formation of COX By-Products in Methanol-to-Aromatics Reaction over Zn/HZSM-5: Significantly Affected by the Chemical State of Surface Zn Species. ChemCatChem, 2019, 11, 4755-4764. 
5. Junhui Li,* Wenxue Ji, Min Liu, Guoqing Zhao, Wenzhi Jia, Zhirong Zhu. New insight into the alkylation-efficiency of methanol with toluene over ZSM-5: microporous diffusibility significantly affects reacting-pathways. Microporous and Mesoporous Materials, 2019, 282, 252-259. (二区)

6. Junhui Li,  Kai Tong,  Zhiwen Xi,  Ying YuanZhonghua Hu, Zhirong Zhu. Highly-efficient conversion of methanol to p-xylene over shape-selective Mg-Zn-Si-HZSM-7 catalyst with fine modification of pore-opening and acidic properties. Catalysis Science & Technology, 2016, 6, 4802-4813.  
7. Junhui Li, Hao Xiang, Min Liu, Qunlong Wang, Zhirong Zhu, Zhonghua Hu. Deactivation mechanism of two typical shape-selective HZSM-5 catalysts for alkylation of toluene with methanol. Catalysis Science & Technology, 2014, 4, 2639-2649.
8. Junhui Li, Hui Xia, Qian Wu, Zhonghua Hu, Zhixian Hao, Zhirong Zhu.Hydrocracking of the thermal pyrolysis oil of municipal wastes over bi-functional Mo-Ni catalyst. Catalysis Today, 2016,
271, 172-178.
9. Junhui Li, Chao Hu, Kai Tong, Hao Xiang, Zhirong Zhu, Zhonghua Hu. CO2 atmosphere-enhanced methanol aromatization over the NiO-HZSM-5 catalyst. RSC Advances, 2014, 4, 44377-44385.
10. Junhui Li, Yanan Wang, Wenzhi Jia, Zhiwen Xi, Huanhui Chen, Zhirong Zhu, Zhonghua Hu. Effect of the external surface of HZSM-5 zeolite on the product distribution in conversion of methanol to hydrocarbons. Journal of Energy Chemistry, 2014, 23, 771-780.

11. Junhui Li, Zhonghua Hu, Yanan Wang, Hao Xiang, Zhirong Zhu. Effect of Steam Treatment on Catalytic Performance of La2O3-HZSM-5 for Methylation of Toluene with Methanol. Advanced Materials Research, 2013, 629, 381-385.

12. Junhui Li, Yanan Wang, Jun He, Zhirong Zhu. Alkylation of Benzene with Ethanol on Zeolites Modified with La2O3. Advanced Materials Research, 2012, 347-353, 3670-3676.

13. Min Liu, Junhui Li, Wenzhi Jia, Mengjiao Qin, Yanan Wang, Kai Tong, Huanhui Chen, Zhirong Zhu. Seed-induced synthesis of hierarchical ZSM-5 nanosheets in the presence of hexadecyl trimethyl ammonium bromide. RSC Advances, 2015, 5, 9237-9240.

14. Chao Hu, Junhui Li, Wenzhi Jia, Min Liu, Zhixian Hao, Zhirong Zhu. Influence of Metallic Modification on Ethylbenzene Dealkylation over ZSM-5 Zeolites. Chinese Journal of Chemistry, 2015, 33, 247-252.

15. Huanhui Chen, Yanan Wang, Qunlong Wang, Junhui Li, Shiqi Yang, Zhiron. Zhu. Bifunctional Organic Polymeric Catalysts with Tunable Acid-base distance and Framework Flexibility. Scientific Reports, 2014, 4, 6475. DOI: 10.1038/srep06475.
16. Wenzhi JiaMin LiuXuewei Lang, Chao Hu, Junhui Li, Zhirong Zhu. Catalytic dehydrofluorination of 1,1,1,2-tetrafluoroethane to synthesize trifluoroethylene over a modified NiO/Al2O3 catalyst. Catalysis Science & Technology, 2015, 5, 3103-3107.

17. Guoqing Zhao, Huanhui ChenJunhui Li, Qunlong Wang, Yanan WangShuwen Ma  and  Zhirong Zhu. Acid-based co-catalysis for oxidative dehydrogenation of ethylbenzene to styrene with CO2 over X zeolite modified by alkali metal cation exchange. RSC Advances, 2015, 5, 75787-75793.

18. Min Liu, Wenzhi Jia, Xu Liu, Junhui Li, Zhirong Zhu. Transalkylation properties of hierarchical MFI and MOR zeolites: direct synthesis over modulating the zeolite grow kinetics with controlled morphology. Catalysis Letters, 2018, Accepted.

19. Min Liu, Wenzhi Jia, Junhui Li, Yanan Wang, Shuwen Ma, Huanhui Chen and Zhirong Zhu. Catalytic Properties of Hierarchical Mordenite Nanosheets Synthesized by Self-Assembly Between Subnanocrystals and Organic Templates. Catalysis Letters, 2016, 146, 249-254.
20. 
龚清,李军辉,* 向浩,赵国庆,朱志荣. 高性能甲苯烷基化合成二甲苯催化剂研究. 燃料化学学报,2019, 47, 806-813.

21. 李军辉,赵国庆,胡中华,朱志荣. 多功能择形催化剂对复杂一锅法反应体系的分子管理. 第十九届全国分子筛学术大会(2017,武汉,口头报告).

22. 李军辉,童凯,向浩,朱志荣. 不同尺寸大小分子筛孔道对MTH反应历程的影响. 第十七届全国分子筛学术大学(2013,银川,口头报告),O65,215-216.

23. 童锴, 李军辉, 奚志文, 朱志荣. 金属氧化物和硅沉积改性ZnO/SiO2/ZSM-5的甲醇择形芳构化反应催化研究. 燃料化学学报,2014,43(2),221-227.
24. 向浩,李军辉,朱志荣. 苯与甲醇烷基化反应催化剂的性能研究. 石油化工,2012,41,269-271.

发明专利

1.甲醇、碳十芳烃与 2-甲基烷基化合成 2,6-二甲基萘方法. CN102001907B.

2.一种焦化苯、甲苯和甲醇烷基化反应选择性合成对二甲苯催化剂.CN103816935B.

3.一种苯和甲醇烷基化反应高选择性合成二甲苯的方法. CN102964201B.

成果获奖


科研成果


学术交流

1. 第十九届全国分子筛学术大会, 2017,武汉,口头报告
2. 第十七届全国分子筛学术大学, 2013,银川,口头报告


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